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291000 Tributylammonium Pyrophosphate CAS: 5975-18-8

Specifications
References
CAS Number
5975-18-8
Grade
Highly Purified
MDL Number
MFCD00136019
Molecular Formula
C₂₄H₅₈N₂O₇P₂
Molecular Weight
548.67
EU Commodity Code
38220090
Shipping Temp
RT
Storage Temp
RT
Pyrophosphoric Acid, compd. with Tributylamine (1:2) (8CI); Bis(tri-n-butylammonium) Pyrophosphate; N,N-Dibutyl-1-butanamine (Diphosphate); Tributylamine, Pyrophosphate; Tributylamine Pyrophosphate

Tributylammonium pyrophosphate is a phosphorylating reagent used in the synthesis of phosphorylated nucleosides, particularly nucleoside triphosphates used as building blocks for the synthesis of DNA, RNA and sugar nucleotides; as well as a source of cellular energy. Nucleoside triphosphates are typically synthesised by treating free nucleosides with phosphorus oxychloride, then adding tributylammonium pyrophosphate to the reaction intermediate, where the lipophilic tributylammonium salt enhances solubility in organic solvents. Additionally, tributylammonium pyrophosphate was used in the preparation of structurally complex dinucleotide-5’-triphosphates.

Synonyms
Pyrophosphoric Acid, compd. with Tributylamine (1:2) (8CI); Bis(tri-n-butylammonium) Pyrophosphate; N,N-Dibutyl-1-butanamine (Diphosphate); Tributylamine, Pyrophosphate; Tributylamine Pyrophosphate
CAS No
5975-18-8
Molecular Formula
C₂₄H₅₈N₂O₇P₂
Molecular Weight
548.67
Appearance
White to off-white powder
Purity
≥98%
Melting Point
78-83°C
Solubility
DMSO (Slightly), Methanol (Slightly), Water (Slightly)
Storage and Stability
May be stored at -20°C
References
Santner et al (2012). The synthesis of 2′-methylseleno adenosine and guanosine 5′-triphosphates. Bioorganic and Medicinal Chemistry 20:2416.; Hollenstein (2012). Nucleoside Triphosphates — Building Blocks for the Modification of Nucleic Acids. Molecules 17:13569-13591.; Abramova et al (2007). A facile and effective synthesis of dinucleotide 5′-triphosphates. Bioorganic and Medicinal Chemistry 15:6549-6555.
USBio References
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